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Iodine thiolate anions

Haloarene chromium tricarbonyl complexes are activated to nucleophilic attack by thiolate anions [58, 59]. High yields of the thioethers are obtained under liquiddiquid two-phase conditions, but optimum yields are achieved under soliddiquid conditions. In many cases the thioether is produced directly but, where the reaction mixture contains thioether and its chromium complex, the thioether can be isolated by degradation of the complex with iodine or an excess of the thiol. Both 1,2- and 1,4-dichlorobenzenes yield only monothioethers, even when an excess of thiolate anion is used. In contrast, 1,3-dichlorobenzenes produce a mixture of the mono- and dithioethers [59]. Aryl allyl thioethers have been produced under catalysed Heck reaction conditions from S-allyl thiocarbamates and iodobenzene [60]. [Pg.37]

The thiolate anion is quantitatively oxidized by iodine to the disulphide , and this method, involving the formation of an unstable sulphenyl iodide, is the basis of the iodometric determination of mercapto groups in a number of compounds . [Pg.145]

The thiolate anion is an intermediate in the oxidation of a thiol by iodine . [Pg.390]


See other pages where Iodine thiolate anions is mentioned: [Pg.375]    [Pg.138]    [Pg.176]    [Pg.289]    [Pg.175]    [Pg.69]    [Pg.205]    [Pg.461]    [Pg.499]    [Pg.300]    [Pg.176]   
See also in sourсe #XX -- [ Pg.456 , Pg.457 ]

See also in sourсe #XX -- [ Pg.456 , Pg.457 ]

See also in sourсe #XX -- [ Pg.456 , Pg.457 ]




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Anions thiolates

Iodine anions

Thiolate

Thiolate anion

Thiolates

Thiolation

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