Iodine PhI

D.L. Rousseau, P.F. Williams Discrete and diffuse emission following two photon excitation of the E-state in molecular iodine. Phys. Rev. Lett. 33, 1369 (1974)... 

Otto B, Schroeder J and Tree J 1984 Photolytic cage effect and atom recombination of iodine in compressed gases and liquids experiments and simple models J. Chem. Phys. 81 202... 

Schwarzer D, Schroeder J and Schroder Ch 2000 Quantum yields for the photodissociation of iodine in compressed liquids and supercritical fluids Z. Phys. Chem. 214... 

Harris A L, Berg M and Harris C B 1986 Studies of chemical reactivity in the condensed phase. I. The dynamics of iodine photodissociation and recombination on a picosecond time scale and comparison to theories for chemical reactions in solution J. Chem. Phys. 84 788... 

Chuang T J, Hoffman G Wand Eisenthai K B 1974 Piooseoond studies of the oage effeot and ooiiision induoed predissooiation of iodine in iiquids Chem. Phys. Lett. 25 201... 

Luther K and Troe J 1974 Photolytio oage effeot of iodine in gases at high pressure Chem. Phys. Lett. 24 85-90 Dutoit J C, Zellweger J M and van den Bergh H 1990 J. Chem. Phys. 93 242... 

Dardi P S and Dahler J S 1990 Microscopic models for iodine photodissociation quantum yields in dense fluids J. Chem. Phys. 93 242-56... 

Steinfeld J I and Klemperer W 1965 Energy-transfer processes in monochromatically excited iodine molecules. I. Experimental resulted. Chem. Phys. 42 3475-97... 

Takemura K, Minomura S, Shimomura O, Fu]ii Y and Axe J D 1982 Structural aspects of solid iodine associated with metallization and molecular dissociation under high pressure Phys. Rev. B 26 998... 

Ocko B M, Wang J and Watson G M 1994 The structure and eiectrocompression of eiectrodeposited iodine monoiayers on Au(111) J.Phys. Chem. 98 897-906... 

Recently, the ring enlargement of 4-hydroxy-2-cyclobutenones 5 was promoted by PhI(OAc)2, a popular and accessible hypervalent iodine reagent (99JOC8995). Thus, when 5a-c (R = Me, Bu, Ph) were treated with a slight excess of PhlfOAcja in dichloromethane at room temperature, the 5-acetoxy-3,4-diethoxyfuranones 13... 

Evidence for a cyclic transition state in iododesilylation of phenyltrimethyl-silane by iodine monochloride (reaction (311), X2 = IC1 giving Phi and SiMe3Cl) has been obtained by comparing rates of chlorodesilylation and iododesilylation in acetic acid at 25 °C743. Good second-order kinetics for the latter reaction were obtained by application of equation (312)... 

The Dess-Martin reagent can be shock sensitive under some conditions and explode > 200°C. Other hypervalent iodine oxidizing reagents are known, including PhI(OAc)2/TEMPO and PhI(OAc)2 supported on alumina with microwave irradiation. 

S. Bratos, P. Mirloup, R. Vuilleumier, and M. Wulff, Time-resolved X-ray diffraction statistical theory and its application to the photo-physics of molecular iodine. J. Chem. Phys. 116(24), 10615-10625 (2002). 

M. Wulff, S. Bratos, A. Plech, R. Vuilleumier, F. Mirloup, M. Eorenc, Q. Kong, and H. Ihee,. Recombination of photodissociated iodine a time-resolved X-ray diffraction study. J. Chem. Phys. 124(3), 034501 (2006). 

J. Zimmerman and R. M. Noyes, The primary quantum yield of dissociation of iodine in hexane solution. J. Chem. Phys. 18(5), 658-666 (1950). 

G. W. Hoffman T. J. Chuang, and K. B. Eisenthal, Picosecond smdies of the cage effect and collision induced predissociation of iodine in liquids. Chem. Phys. Lett. 25(2), 201-205 (1974). 

Figure 8.10 STM images showing coexisting c(2 x 2)/(a) and phenyl adsorbates at a Cu(110) surface, (a) After 180L Phi, Vs= -2.88 V, 7-r=1.41nA note the offset between the maxima in the iodine lattice either side of the phenyl chain showing that the phenyl groups are situated in a grain boundary in the iodine lattice, (b) 3D representation of (a) showing clearly the 1(a) maxima, (c) Schematic model of the coexisting iodine and phenyl lattices. (Reproduced from Ref. 28).

Ding, R., J. L. Grant et al. (1988). Carotenoid cation radicals produced by the interaction of carotenoids with iodine. J. Phys. Chem. 92 4600-4606. 

Baptist, J.P., D.E. Hoss, and C.W. Lewis. 1970. Retention of chromium-51, iron-59, cobalt-60, zinc-65, strontium-85, niobium-95, indium-114m, and iodine-131 by the Atlantic croaker (Micropogon undulatus). Health Phys. 18 141-148. 

Markham, O.D., T.E. Hakonson, and J.S. Morton. 1983. Iodine-129 in mule deer thyroids in the Rocky Mountain west. Health Phys. 45 31-37. 

F. Huang, A.G. MacDiarmid, and B.R. Hsieh, An iodine-doped polymer light-emitting diode, Appl. Phys. Lett., 71 2415-2417 (1997). 

Marcus, R. A and Rice, O. K., The kinetics of the recombination of methyl radicals and iodine atoms.. /. Phys. Chem 55, 894 (1951). Marcus, R. A., Unimolecular dissociations and free radical recombination reactions. J. Chem. Phys. 20, 359 (1952). 

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