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Inversions, of alcohol

When a carboxylic acid is used as the nucleophile, simple ester hydrolysis releases the alcohol, providing an inversion of alcohol stereochemistry. [Pg.434]

Further interesting findings are the dependence of the 46/47 product ratio on the concentration of alcohol. Plots of 46/47 versus the inverse of alcohol concentration gave straight lines at the initial stage of the reaction. This was observed when 45 was irradiated in the presence of various amounts of alcohols in acetonitrile. The slope depended remarkably on the alcohol, i.e. the slopes were 4.6 for MeOH, 9.2 for n-PrOH and 32 for i-PrOH. An infinitely large slope was estimated for z-BuOH, because z-BuOII gave only the syn compound. [Pg.848]

INVERSION, OF ALCOHOLS Cesium propionate. Triphenylphosphine-Diethyl azodicarboxylate. [Pg.661]

Oxidative cleavage of silicon-carbon bonds leading to alcohols 1.123 Inversion of alcohols... [Pg.2]

Inversion of alcohols By chloromesylation (with ClCH2S02Cl/py), treatment with CsOAc/18-crown-6, and hydrolysis, a secondary alcohol is converted into its enantiomer. [Pg.70]

Applications Inversion of alcohols—intramolecular lactone formation... [Pg.687]

See other pages where Inversions, of alcohol is mentioned: [Pg.124]    [Pg.124]    [Pg.434]    [Pg.295]    [Pg.709]    [Pg.925]    [Pg.930]    [Pg.2]    [Pg.19]    [Pg.22]    [Pg.78]    [Pg.124]    [Pg.697]    [Pg.151]    [Pg.242]    [Pg.680]    [Pg.2]    [Pg.19]   
See also in sourсe #XX -- [ Pg.103 ]



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Inversion alcohol

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