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Intramolecular reactions organic radical ions

The synthesis of complex ring-systems is still a challenge in organic chemistry. With the exception of cycloadditions, the ring-building key step is always an intramolecular bond formation. In PET-initiated reactions, this step can be an addition (or recombination) reaction of a radical or radical ion or a nucleophilic... [Pg.201]

Phys. 74 6746 (1981) b) G. L. Gloss, L. T. Calcaterra, N. J. Green, K. W. Penfield, and J. R. Miller, Distance, stereoelectronic effects, and the Marcus inverted region in intramolecular electron transfer in organic radical anions, J. Phys. Chem. 90 3673 (1986). a) S. Larsson, Electron transfer in chemical and biological systems. Orbital rules for nonadiabatic transfer, J. Am. Chem. Soc. 103 4034 (1981) b) S. Larsson, n Systems as bridges for electron transfer between transition metal ions, Chem. Phys. Lett. 90 136 (1982) c) S. Larsson, Electron transfer in proteins, J. Chem. Soc., Faraday Trans. 2 79 1375 (1983) d) S. Larsson, Electron-exchange reaction in aqueous solution, J. Phys. Chem. 88 1321 (1984) e) S. Larsson,... [Pg.171]


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Organic Radical Reactions

Organic ions

Organic radicals

Radical reactions intramolecular

Radicals intramolecular

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