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Internal derived reactor design

Suspension polymerization of VDE in water are batch processes in autoclaves designed to limit scale formation (91). Most systems operate from 30 to 100°C and are initiated with monomer-soluble organic free-radical initiators such as diisopropyl peroxydicarbonate (92—96), tert-huty peroxypivalate (97), or / fZ-amyl peroxypivalate (98). Usually water-soluble polymers, eg, cellulose derivatives or poly(vinyl alcohol), are used as suspending agents to reduce coalescence of polymer particles. Organic solvents that may act as a reaction accelerator or chain-transfer agent are often employed. The reactor product is a slurry of suspended polymer particles, usually spheres of 30—100 pm in diameter they are separated from the water phase thoroughly washed and dried. Size and internal stmcture of beads, ie, porosity, and dispersant residues affect how the resin performs in appHcations. [Pg.386]

Much information is available on the deformation and fatigue behavior of simple thick-walled cylinders [10-17], but it must be remembered that most process reactors will not be a simple hollow cylinder. Components such as connectors, threads and sleeves, windows, and removable closures make a complete analytical solution for a high-pressure system design problem quite involved. Useful design criteria for thick-walled vessels can be derived, however, under the assumption that the material of which the vessel is made is isotropic and that the cylinder is long (more than five diameters) and initially free from stress. The radial and tangential stresses in the walls are then only functions of the radius coordinate (r) and the internal pressure. Given the outer-to-inner wall radius ratio as o/i = w, and the yield point (To) of the material, the yield pressure (py) is... [Pg.69]


See other pages where Internal derived reactor design is mentioned: [Pg.27]    [Pg.520]    [Pg.435]    [Pg.100]    [Pg.548]    [Pg.562]    [Pg.53]    [Pg.548]    [Pg.263]    [Pg.37]    [Pg.146]    [Pg.173]    [Pg.48]    [Pg.69]   
See also in sourсe #XX -- [ Pg.345 ]




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