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Interligand oxygen transfer

Interligand oxygen transfer is a rearrangement that occurs between coordinated ligands on a metal framework. However, because of the importance of this class of reactions, it is considered here as a separate subject. [Pg.384]

The synthesis of K2[Pt(N02)6l involves oxidation of K2[Pt(N02)4l with nitric acid in the presence of nitrogen oxides. The reaction proceeds via the intermediate, K2[Pt(N02 4N0(N03)], where redistribution of oxygen between nitrosyl and nitrate ligands results in product formation.77 [Pg.384]

The redistribution of oxygen between ligands in the dimethyl sulfoxide complex, [Pt(N03)2(PPh2CF3)(Me2S0)], proceeds similarly,79 Eq. 11.11  [Pg.384]

Such rearrangement reactions are presumably driven by the high oxophilidty of silicon. / [Pg.385]

See other pages where Interligand oxygen transfer is mentioned: [Pg.590]    [Pg.384]    [Pg.590]    [Pg.384]    [Pg.315]    [Pg.538]    [Pg.538]    [Pg.538]    [Pg.397]    [Pg.397]   


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Oxygen transferate

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