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Interface under pressure field effect

Because of the short lifetime of ions in gaseous atmospheres, even at low pressure, gas-phase IR measurements are limited to adsorption of neutral molecules. Electrochemical applications of the IR method offer the interesting possibility of providing data on the adsorption properties of charged particles (Secs. 8 and 9). In the electrochemical environment the applied potential allows ionic adsorbates to be studied under energetically controllable conditions. Otherwise the electrochemical double layer offers exceptional conditions to investigate the Stark effect on vibrational transitions by setting tunable electric fields of the order of 10 V cm at the interface. This phenomenon will be discussed in Sec. 10. [Pg.145]

See other pages where Interface under pressure field effect is mentioned: [Pg.1113]    [Pg.374]    [Pg.51]    [Pg.31]    [Pg.46]    [Pg.297]    [Pg.20]    [Pg.57]    [Pg.251]    [Pg.382]    [Pg.320]    [Pg.230]    [Pg.264]    [Pg.200]    [Pg.467]    [Pg.799]    [Pg.806]    [Pg.140]    [Pg.49]    [Pg.2781]    [Pg.771]    [Pg.741]    [Pg.148]    [Pg.55]    [Pg.797]    [Pg.509]    [Pg.515]    [Pg.426]    [Pg.163]    [Pg.211]    [Pg.419]    [Pg.285]    [Pg.289]    [Pg.297]   
See also in sourсe #XX -- [ Pg.46 , Pg.49 ]



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Effective interface

Interface effects

Interface pressure

Pressure field

Under-pressure

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