Insights into Solution Chemistry from High Pressure Electrochemistry

Insights into Solution Chemistry from High Pressure Electrochemistry 

Just as the effect of pressure P on an equilibrium constant K can be expressed in terms of a volume of reaction AV 

A particular virtue of pressure-tuning is that kinetically relevant solvent proper- 

Much of our earlier work on pressure effects on the kinetics of electron transfer reactions focused upon the rate constants kex and corresponding volume of activation for self-exchange reactions 

Pressure Effects on the Kinetics of Self-Exchange Reactions 

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I 5 Insights into Solution Chemistry from High Pressure Electrochemistry... 

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