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Inducing factors complex formation with inhibitors

Mixed complex formation has been postulated in the oxidation of sulphite catalysed by transition-metal ions. Several reactions are observed in the presence of copper(ii). The auto-oxidation rate is catalysed with formation of the species [00(803)202] " as intermediate. In the presence of propan-2-ol (ROH), however, an inhibition reaction, dependent on [SOs ] and [ROH], is observed. Induced oxidation of the inhibitor by copper(n) is also a factor, the rate being a function of [Cu ]. In the latter system the complex [Cu(SO )-(R0H)02] is considered as the reactive species,... [Pg.96]

See other pages where Inducing factors complex formation with inhibitors is mentioned: [Pg.51]    [Pg.329]    [Pg.315]    [Pg.674]    [Pg.79]    [Pg.85]    [Pg.106]    [Pg.142]    [Pg.169]    [Pg.119]    [Pg.343]    [Pg.93]    [Pg.53]    [Pg.118]    [Pg.169]    [Pg.176]    [Pg.185]    [Pg.155]    [Pg.122]    [Pg.577]    [Pg.96]    [Pg.119]    [Pg.269]    [Pg.125]    [Pg.53]    [Pg.257]    [Pg.177]    [Pg.135]   
See also in sourсe #XX -- [ Pg.268 , Pg.269 ]



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Factor inhibitor

Formation factor

Inducing factors

With Complex Formation

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