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Indium-nitrogen rings

ALUMINIUM-, GALLIUM- AND INDIUM-NITROGEN RINGS 9.4.1 Unsaturated Systems... [Pg.135]

Figure 8.9 Representation of the dimeric indium azatrane derivative [ln N(CH2 CH2NMe)i)]2 highlighting the central (lnN)2 ring in bold. Indium and nitrogen atoms are shown as black spheres and carbon atoms are white. Selected bond lengths Inl-NI 2.063(3), In1-N22.393(3), Int-N62.083(3), In1-N72.099(2), lnl-N82.350(3), In2-N1 2.456(3), In2-N2 2.224(3), In2-bl3 2.208(3), In2-N4 2.327(3), In2-N5 1.960(3) A... Figure 8.9 Representation of the dimeric indium azatrane derivative [ln N(CH2 CH2NMe)i)]2 highlighting the central (lnN)2 ring in bold. Indium and nitrogen atoms are shown as black spheres and carbon atoms are white. Selected bond lengths Inl-NI 2.063(3), In1-N22.393(3), Int-N62.083(3), In1-N72.099(2), lnl-N82.350(3), In2-N1 2.456(3), In2-N2 2.224(3), In2-bl3 2.208(3), In2-N4 2.327(3), In2-N5 1.960(3) A...
Figure 3 represents the only dimer formed in this series of metallacycles. The coordination number of the indium atom is increased by interaction with the nitrogen atom of a second molecule. The dimer 41 has a center of inversion and three edge-fused four-membered rings. This type of structure is very common in metallacycles that are derived from the ligand 25 (5(5). The central N2In2 ring is almost square-planar [In-N = 2.27(1) A] and the In-C dis-... [Pg.282]

Indium diphthalocyanine In(Pc)2 contains sandwich-type molecules in which the indium atom is eight-coordinate by the isoindole nitrogens of two phthalocyanie rings. The distance between the phthalocyanie planes in this sandwich macromolecule is equal to 274.1pm, and the two phthalocyaninato moieties are rotated about 41.2(4)° with respect to each other. ... [Pg.1682]

See other pages where Indium-nitrogen rings is mentioned: [Pg.336]    [Pg.397]    [Pg.20]    [Pg.820]    [Pg.305]    [Pg.142]    [Pg.243]    [Pg.244]    [Pg.253]    [Pg.528]    [Pg.702]    [Pg.826]    [Pg.661]    [Pg.6004]    [Pg.372]    [Pg.139]    [Pg.1681]    [Pg.6003]    [Pg.543]    [Pg.374]    [Pg.876]    [Pg.1033]    [Pg.71]    [Pg.93]    [Pg.62]    [Pg.62]    [Pg.394]    [Pg.6]    [Pg.28]   
See also in sourсe #XX -- [ Pg.136 ]



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Indium nitrogen

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