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Inclusion of Correlation in Density Theory

recognizing that from this theorem the exchange and correlation energy density, exc say, is a unique functional of the density, one now writes for the [Pg.131]

The Euler equation of the variation problem now involves the functional derivatives of the single-particle kinetic energy density tr corresponding to the exact many-body density p(r), and the exchange and correlation energy density exc. Such a minimization of equation (145) yields immediately [Pg.132]

Because of the definition of tr which was adopted, this has the form of singleparticle theory, but with potential energy71 72 [Pg.132]

Evidently then equation (147) takes the approximate, but explicit, form [Pg.132]


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