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Hydroxycarboxylate ligands

Stability constants for calcium complexes of a selection of hydroxycarboxylate ligands are listed in Table VII (239,246,272-274). For tartrate, malate, and citrate stabilities decrease in the expected order Ca2+> Ba2+> Ra2+ (231,275). The stability constant for the complex of pyruvate (logiOifi 0.8 (273)) is similar to that for acetate calcium complexes of a-ketoglutarate and of oxaloacetate are somewhat more stable (logio-Ki = 1.3, 1.6 respectively (273)). The sequence logio-Ki = 3.0, 1.4, 1.1, 0.6 for the dicarboxylate ligands oxalate, malonate, succinate,... [Pg.279]

Biagioli, M., L. Strinna-Erre, G. Micera, A. Panzanelli, and M. Zema. 2000. Molecular structure, characterization and reactivity of dioxo complexes formed by vana-dium(V) with a-hydroxycarboxylate ligands. Inorg. Chim. Acta 310 1-9. [Pg.75]

Much of the known detail on the hydroxycarboxylate ligands refers to the redox properties of aqueous alkaline solutions and especially to electrochemical studies on the oxidation of the Mn species of glyceric, tartaric, gluconic, glucaric and citric acids to Mn and For each... [Pg.89]


See other pages where Hydroxycarboxylate ligands is mentioned: [Pg.320]    [Pg.109]    [Pg.146]    [Pg.163]    [Pg.23]    [Pg.807]    [Pg.520]    [Pg.465]    [Pg.89]    [Pg.2334]    [Pg.2333]    [Pg.1111]    [Pg.2359]    [Pg.109]    [Pg.146]    [Pg.163]   


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Hydroxycarboxylates

Hydroxycarboxylic

Stability constants hydroxycarboxylate ligands

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