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Hydroxy validamine

Microbial degradation of validamycin A (8) with a cell suspension of Pseudomonas dentrificans afforded validamine (202) and valienamine (203). Hydrogenolysis of validamycin B, followed by acid hydrolysis, yielded hydroxy validamine (204). Valiolamine (205) was isolated and shown to be a component of validamycin G. ° Biosynthesis of these carba-glycosylamines was extensively studied, and the intramolecular aldol addition of the... [Pg.52]


See other pages where Hydroxy validamine is mentioned: [Pg.85]    [Pg.437]    [Pg.439]    [Pg.85]    [Pg.437]    [Pg.439]   
See also in sourсe #XX -- [ Pg.10 , Pg.13 , Pg.189 , Pg.195 , Pg.197 , Pg.518 ]




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Validamines

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