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Hydrolysis diagnostic test

To prove their hypothesis, Bamford and Block (51) applied the diagnostic test previously designed by Gold and Jefferson (58) in their studies of hydrolysis of carboxylic anhydrides catalysed by tertiary bases. The technique employed involves the use of a series of tertiary bases having different relative abilities to assodate with Lewis acids and to act as Bronsted bases. Pyridine, a-picoline and 2,6-lutidine form... [Pg.36]

In 1951, Bender provided the first diagnostic test of mechanism for these reactions. The alkaline hydrolysis of several benzoate esters, aBAc2 reaction, was studied with esters enriched in at the carbonyl oxygen. If the Sn2 mechanism in Eq. (6) is operative, no exchange with the solvent during hydrolysis would be expected, because the carbonyl oxygen does not engage in any reversible step. The tetrahedral intermediate... [Pg.2041]

See other pages where Hydrolysis diagnostic test is mentioned: [Pg.510]    [Pg.20]    [Pg.523]    [Pg.313]    [Pg.241]    [Pg.182]    [Pg.437]    [Pg.293]    [Pg.128]    [Pg.128]   
See also in sourсe #XX -- [ Pg.2041 ]



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Diagnostic testing

Hydrolysis test

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