Hydrolysis constant of, III

In 1961, Roig and Dodson carried out a further study of the exchange in perchlorate media under identical conditions (25 °C, fi = 3.0 M) to those in the Tl(III) hydrolysis studyThe isotope was used, with a separation procedure based on extracting TI(III) from reaction mixtures with either methyl isobutyl ketone or diethyl ether. The exchange was examined in the absence of light, and a correction procedure to eliminate the catalytic effects of traces of chloride ions was used since Tl(III) concentrations of 10 M were necessary at the very low acidities employed. Using the known values of the first and second hydrolysis constants of Tl(III) (K2 and K3)... 

Garcia Rodenas, L. and Liberman, S.J. (1991) Hydrolysis of gadolinium(III) in light and heavy water. Talanta, 38, 313—318. Gonzalez-Mendoza, R., Lopez-Gonzalez, H., and Rojas-Hernandez, A. (2010) Spec-trophotometric determination of the first hydrolysis constant of praseodymium(III). 

Jimenez-Reyes, M. and Solache-Rios, M. (1994) The first hydrolysis constant of Eu(III) in 4 M ionic strength at 303 K. Radiochim. Acta, 64, 201-203. 

Hydrolysis constants of pluto-nium(in) and americium(III). Radiochim. Acta, 30, 37—40. 

There have been a number of studies that have obtained the hydrolysis constants of americium(III) from solubility measurements. In addition, there have also been a few studies that have obtained constants using other techniques. The data are listed in Table 9.22. 

---