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Hydrogenolysis side products from

Other starting materials for adipic acid include butadiene and 1,4-disubsti-tuted-2-butene, which involves dicarbonylation with palladium chloride. Polar, aprotic, and nonbasic solvents are preferred for this reaction to avoid unwanted side products from hydrogenolysis or isomerization. [Pg.31]

The same corynoline analog (214) was obtained more conveniently through photolysis in the presence of nitrosobenzene. Addition of nitrosobenzene to 208 from the opposite side of the methyl group resulted in the B/C-trans adduct 215. Reduction of 215 with sodium borohydride followed by acidic treatment gave the B/C-cis product 217 via 216. Hydroxylation of 217 with performic acid and hydrogenolysis of the diol 218 completed the synthesis of 214 (126). [Pg.172]

See other pages where Hydrogenolysis side products from is mentioned: [Pg.7]    [Pg.156]    [Pg.237]    [Pg.212]    [Pg.192]    [Pg.310]    [Pg.10]    [Pg.355]    [Pg.80]    [Pg.1047]    [Pg.301]    [Pg.49]    [Pg.1047]    [Pg.63]    [Pg.124]    [Pg.36]    [Pg.52]    [Pg.66]    [Pg.23]    [Pg.144]    [Pg.174]    [Pg.147]    [Pg.30]    [Pg.54]    [Pg.66]    [Pg.771]    [Pg.773]    [Pg.69]    [Pg.420]    [Pg.280]    [Pg.231]    [Pg.252]    [Pg.88]    [Pg.439]    [Pg.430]    [Pg.40]    [Pg.249]    [Pg.555]    [Pg.354]    [Pg.119]    [Pg.306]    [Pg.259]    [Pg.260]    [Pg.268]    [Pg.33]    [Pg.19]    [Pg.172]    [Pg.75]   
See also in sourсe #XX -- [ Pg.42 ]



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Products from hydrogenolysis

Side product

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