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Reactions with Oxygen-Hydrogen Bonds

If the alkene or alkadiene has at least one hydrogen on the carbon adjacent to the double bond, reaction with singlet oxygen may give hydroperoxides. The mechanism of this reaction is related to [4 + 2] cycloadditions and is presumed to occur through a HLickel pericyclic transition state (see Section 21-10D) ... [Pg.1392]

Our studies have also shown that water will react spontaneously with some metals or can be caused to react further by photoexcitlng the adduct. Reaction in all cases leads initially to metal insertion into the hydrogen-oxygen bond. This metal hydroxy-hydride will, for certain metals, undergo photolysis to... [Pg.363]


See other pages where Reactions with Oxygen-Hydrogen Bonds is mentioned: [Pg.14]    [Pg.78]    [Pg.211]    [Pg.3035]    [Pg.677]    [Pg.94]    [Pg.322]    [Pg.237]    [Pg.209]    [Pg.3034]    [Pg.677]    [Pg.291]    [Pg.36]    [Pg.49]    [Pg.136]    [Pg.578]    [Pg.324]    [Pg.719]   


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Bonds with hydrogen

Hydrogen bonding with oxygen

Hydrogen with oxygen

Hydrogen-oxygen bond

Hydrogen/oxygen reaction

Hydrogenation reaction with

OXYGEN hydrogen

Oxygen hydrogen bonded

Reaction with hydrogen

Reaction with oxygen

Reactions hydrogen-oxygen reaction

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