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Hydrogen cyanide bonding molecular orbitals

Formally, the lone pairs on molecular nitrogen, hydrogen cyanide, and carbon monoxide are sp hybrid orbitals, whereas NLMO hybridizations calculated even lower p contributions. Hence, these lone pairs have low directionality, the electron density remains close to the coordinating atom and interaction between the lone pair and the Be2+ is comparatively weak. The Be-L bonds are easily disrupted and ligand exchange consequently can proceed with a low activation barrier. A high degree of p character, on the other hand, means that the lone pair is directed toward beryllium, with electron density close to the metal center, and thus well suited for coordination. [Pg.555]

Problem 16.1 Hydrogen cyanide, HCN, is isoelectronic with the N2 molecule. The Lewis structure would presumably be H-C=N . Do you expect the molecule to he linear or bent Give a description of the bonding in terms of 2c molecular orbitals. [Pg.244]


See other pages where Hydrogen cyanide bonding molecular orbitals is mentioned: [Pg.318]    [Pg.853]    [Pg.853]    [Pg.19]    [Pg.323]    [Pg.35]   
See also in sourсe #XX -- [ Pg.35 ]




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