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Hydroboration of Olefins -Isopinocampheol

HYDROBORATION OF OLEFINS (+)-ISOPINOCAMPHEOL, 52, 59 Hydroboration-oxidation of olefins, 53, 83... [Pg.60]

Isopinocampheol has been prepared by hydrogenation of irams-pinocarveol with a neutral nickel catalyst at 70-100°. The hydroboration reaction provides a convenient procedure for the conversion of olefins to alcohols without rearrangement and with a predictable stereochemistry. The reaction has been applied to a large number of olefins of widely different structures. The results obtained support the proposed generaliza-tit)ii that hydroboration involves an anborane from the less hindered side of the double bond. ... [Pg.111]


See other pages where Hydroboration of Olefins -Isopinocampheol is mentioned: [Pg.110]    [Pg.59]    [Pg.110]    [Pg.59]   
See also in sourсe #XX -- [ Pg.52 , Pg.59 ]

See also in sourсe #XX -- [ Pg.52 , Pg.59 ]

See also in sourсe #XX -- [ Pg.52 , Pg.59 ]




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HYDROBORATION ISOPINOCAMPHEOL

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Isopinocampheol

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