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Hydrido-bridged platinum complex

A New Class of Hydrido-Bridged Platinum Complex with Application in Catalysis... [Pg.118]

Most recently, Milstein and coworkers reported a new type of homogeneous catalytic reaction that generates silanones from secondary silanols under extremely mild conditions. The platinum complex (dmpe)Pt(Me)OTf) (27) (dmpe = Me2PCH2CH2PMe2, OTf = OSO2CF3 was treated with an equimolar amount of the silanol, (i-PrhSilKOII) (28), in acetone to yield a new dimeric hydrido-bridged complex 29 and the trimer 30 of diisopropylsilanone, 31 (Scheme 12)29. [Pg.1074]

Recent studies indicate the reaction of platina-/3-diketone with bipyridines via oxidative addition yields the diacyl hydrido Pt(IV) complex. Further ligand abstraction may result in H bond bridged dimer and a double-deck dimer through Pt Pt interaction (Scheme 17). On the other hand, the prototype of unsupported cis- diacyl platinum(II) species was obtained either via nucleophilic addition to cationic acyl carbonyl complexes or CO insertion into a trans acyl alkyl complex (Scheme 18). In the latter process for propionyl methyl or acetyl ethyl complex. [Pg.3905]

See other pages where Hydrido-bridged platinum complex is mentioned: [Pg.120]    [Pg.122]    [Pg.124]    [Pg.126]    [Pg.128]    [Pg.120]    [Pg.122]    [Pg.124]    [Pg.126]    [Pg.128]    [Pg.555]    [Pg.169]    [Pg.122]    [Pg.127]    [Pg.127]    [Pg.127]    [Pg.649]    [Pg.314]    [Pg.216]    [Pg.50]    [Pg.186]    [Pg.707]    [Pg.120]    [Pg.121]    [Pg.123]    [Pg.121]    [Pg.189]    [Pg.67]    [Pg.211]    [Pg.1123]    [Pg.98]    [Pg.176]    [Pg.162]    [Pg.186]   


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Hydrido-bridged

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