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Hydride relationships between carbonyl

Relationships between Carbonyl Hydride Clusters and Interstitial Hydrides... [Pg.8]

The close relationship between alcohols and carbonyls has become apparent in this chapter. Oxidation of alcohols produces the carbonyl group and reduction of the carbonyl, by hydrides or organometallic reagents, produces the alcohol. Protecting groups for alcohols, aldehydes, and ketones were introduced in Section 16.10. [Pg.816]

The relationship between metal carbonyl hydrides and dihydrogen complexes of metal carbonyl derivatives has been further explored.The interactions of d ML5 fragments with H2 have been studied by EHMO methods,and the structures and some reactions of n -H2 complexes of Cr, Mo, W, Fe and Co carbonyl derivatives examined.Intramolecular ligand rearrangements in [M(C0)5H] anions (M = Cr or Mo) have been investigated using variable temperature n.m.r. A twist mechanism that provides a pathway for intramolecular axial-equatorial CO exchange is favoured.The catalytic role of these... [Pg.153]

See other pages where Hydride relationships between carbonyl is mentioned: [Pg.113]    [Pg.378]    [Pg.799]    [Pg.353]    [Pg.271]    [Pg.26]    [Pg.3341]    [Pg.20]    [Pg.186]    [Pg.102]    [Pg.80]    [Pg.1088]   


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