Hydration of halide ions

The strong hydration of halide ions in water is partly due to outer-sphere effects. Oxo anions in aqueous solution may complex with outer-sphere water molecules as in the hydrated chromate and permanganate ions ... 

A similar kinetic model has been developed for the measurement of ion complex formation kinetics and energies involving both dissociative and nondissociative electron capture, for example, the hydration of halide ions and of 02( ). The ratio of negative ions observed in NIMS can be used to determine energies of complex formation. In this case the sequential formation of the higher complexes must be added to the kinetic model. These studies are important because they demonstrate that the API mass spectrometer can be used to measure thermodynamic quantities. When we use the data for hydrates of 02(—) as an example, the kinetic expression is given by... 

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See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

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