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Hybrid “molecule/surface” species

However, NO can also interact with surface metal centres on metal oxides, giving rise to surface mononitrosyl, gem-dinitrosyl and trinitrosyl species. When the cation or the metal atom contains, besides empty orbitals, full or partly filled d-type orbitals, they can interact with the 7r -type orbitals of NO molecules, via a TT-type electron back-donation. This gives rise to bent nitrosyls, where N is Hkely sp hybrid and the NO stretching frequency is decreased. [Pg.165]

See other pages where Hybrid “molecule/surface” species is mentioned: [Pg.3]    [Pg.3]    [Pg.391]    [Pg.472]    [Pg.78]    [Pg.127]    [Pg.11]    [Pg.197]    [Pg.647]    [Pg.808]    [Pg.226]    [Pg.249]    [Pg.88]    [Pg.284]    [Pg.334]    [Pg.397]    [Pg.72]    [Pg.8]    [Pg.120]    [Pg.506]    [Pg.285]    [Pg.96]    [Pg.194]    [Pg.765]    [Pg.167]    [Pg.180]    [Pg.213]    [Pg.237]    [Pg.375]    [Pg.363]    [Pg.120]    [Pg.308]    [Pg.55]    [Pg.114]    [Pg.434]    [Pg.552]    [Pg.174]    [Pg.514]    [Pg.51]    [Pg.86]    [Pg.220]    [Pg.78]    [Pg.208]    [Pg.26]    [Pg.155]    [Pg.489]    [Pg.100]    [Pg.224]    [Pg.196]    [Pg.341]   
See also in sourсe #XX -- [ Pg.3 ]



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Molecules hybrid

Surface molecules

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