Homogenizing of Melts

Quantitative description of the degree of inhomogeneity of a glass is difficult. Density or refractive index measurement on crushed glasses can be used as a relative measurement of intensity of inhomogeneity. Visual examination of a pattern consisting of dark, parallel lines 

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Inadequate mixing Check homogeneity of melt and plasticisation capacity of cylinder. 

Sato et al. " measured the viscosities of some binary and ternary alkali carbonates. Since melt creep must be prevented, a highly sintered alumina crucible was used instead of a gold-plated nickel crucible. Homogeneity of a mixture sample was achieved by gas bubbling. A laser beam is combined with a computer-assisted time counter to obtain the logarithmic decrement. Roscoe s equationi3i has been used for calculation of the viscosity, while it has been claimed by Abe et al. that the viscosities calculated from Roscoe s equation are 0.6-1.5% lower than those from more rigorous equations. 

It should be emphasized that the deviations from the logarithmic correlation obey the normal distribution statistics, allowing one to apply convenient statistical procedures to analytical measurement results. As will be shown below, the logarithmic linear correlation rule was observed for all types of geo-chemical samples, i. e., snow, air, water, and soil. The correlation analysis of the elemental composition of melted-snow fractions showed with confidence level 95% that no significant discrepancy exists between the element composition within the correlation curves (see Table 1) and the corresponding variances are thus homogeneous for any two randomly chosen samples (i. e., points of the territory). 

Both correlation and variance analysis results showed that the hypothesis on the linear correlation between inter-laboratory data and the homogeneity of the corresponding variances is true for all data sets, at the for 95% confidence level. Table 2 presents a typical example of such a comparison. Based on the detected property of homogeneous variances, root-mean-square standard deviation, S, for all melted snow samples was estimated S = 0.32 0.06 for 95% confidence level [3]. 

Instead of using high-temperature melting to make the precursor alloys, an alternative wet chemistry technique has been proposed where nickel(O) and aluminum coordination compounds are blended together and treated to give nanocrystalline NiAlx alloys with 1 < x < 3 [48], The alloys are leached in the same way as standard skeletal catalysts. Catalysts with higher activity than commercially available Raney nickel have been prepared by this technique, with the activity attributed to the finer structure and homogeneity of the alloys [48,49],... 

In figure 2 the dependence h(l]) is shown, from which follows rapid decrease h or increase of homogeneity of reactive medium at Tt raising. At 7 540 K exponent h=0, i.e., reactive medium becomes homogeneous. The authors [1] have show that the melting temperature Tm for studied polyimides is about equal to 800 K. On the basis of the known law of two-thirds... 

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