Homogeneous Pyrolants

The author proposed organometaUic polymers constituted from electropositive metals and fluorinated carbon chains as homogeneous pyrolants [22]. 

Referring to Section 3.5, the burning mode of an Mg-Tf pyrolant can be understood by the use of Eqs. (3.73)-(3.76). If one assumes a homogeneous condensed phase, the heat balance at the burning surface is represented by... 

When AP particles are added to GAP-AN pyrolants, a number of luminous flame-lets are formed above the burning surface. These flamelets are produced as a result of diffusional mixing between the oxidizer-rich gaseous decomposition products of the AP particles and the fuel-rich gaseous decomposition products of the GAP-AN pyrolants. Thus, the temperature profile in the gas phase increases irregularly due to the formation of non-homogeneous diffusional flamelets. 

Since pyrrole and its derivatives form very stable conducting surfaces, Za-gal, Bedioui, and coworkers used ultramicro-carbon-fiber electrode modified with polypyrrole-dopped cobalt-tetrasulfonated phthalocyanine for the electrocatalytic oxidation of 2-ME The resulting electrode was stable and showed a detection limit of 8 10 M. Pyrolle substituted phthalocyanines have been used for the analysis of cysteine. Electrocatalytic behavior of MPc complexes has also been examined under homogeneous conditions. Water soluble OMo (OH)TSPc catalyzed the oxidation of cysteine under homogeneous conditions. ... 

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