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High-Temperature Limit for Vibrational Heat Capacity

HIGH-TEMPERATURE LIMIT FOR VIBRATIONAL HEAT CAPACITY [Pg.337]

We can see the vibrational heat capacity approaches R asymptotically but the example for HCl shows that at room temperature, the actoal heat capacity can be quite low. What does the formula [Pg.337]

Thus we see that mathematically the vibrational heat capacity does tend toward R at high temperatures but if the bond is very stiff the value can be considerably smaller than R at room temperature. [Pg.337]




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Capacity limit

Capacity-limited

Heat limitation

High heat capacity

High limitations

High limiters

High temperature heat capacity

High temperature limit

High temperature limitations

High-3-limit

Limitation capacity

Limitations for

Limiting temperatures

Temperature heat capacities

Temperature limitations

Temperature limiter

Temperature vibrational

Vibrational heating

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