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High spins asymmetrical lineshape

Experimentally the continuous-wave (CW) EPR experiment is a field-swept experiment in which the microwave frequency (Vc) is held constant and die magnetic field varied. Computer simulations performed in field space assume a symmetric lineshape function,/in Eq. (3) (J(B - B es), CTg), which must be multiplied by dv/dB and assume a constant transition probability across a given resonance [1,29]. Sinclair and Pilbrow [30,31] have described the limitations of fliis approach in relation to asymmetric lineshapes observed in high-spin Cr(III) spectra and the pres-... [Pg.109]

See other pages where High spins asymmetrical lineshape is mentioned: [Pg.132]    [Pg.127]    [Pg.587]    [Pg.14]    [Pg.38]    [Pg.228]    [Pg.71]    [Pg.209]    [Pg.524]   
See also in sourсe #XX -- [ Pg.210 ]



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