High performance membrane dendrimer

Taniguchi, I., Duan, S., Kazama, S., Fujioka, Y. (2008). Facile fabrication of a novel high performance CO2 separation membrane immobilization of poly(amidoamine) dendrimers in poly(ethylene glycol) networks. Journal of Membrane Science, 322, 277—280. 

Another example is the palladium catalyzed allylic substitution of 3-phenyl-2-propenyl-carbonic acid methyl ester to yield iV-(3-phenyl-2-propenyl)morpho-line reported by Reetz, Kragl and co-workers. This reaction was performed in the presence of phosphino-terminated amine dendrimers [17, 18] loaded with Pd11 cations as shown in Scheme 10. For this particular dendrimer with a molecular weight of 10 212 g/mol, a retention of 0.999 per residence time [35] was estimated in a membrane reactor with a SELRO MPF-50 membrane. It must be noted that a very high retention is a prerequisite for a continuous operating system, since a small leaching of the dendrimer leads to an exponential decrease in the amount... 

---