High NO, Limit

Finally, substituting (6.19) into (6.9), the rate of O3 production in the high NO limit is 

Therefore, in the high NO limit, the rate of 03 production increases linearly with both the CO concentration and the rate of HO generation but decreases with increasing NO. Since ample NO exists, the rate of the overall photochemical cycle is controlled by the CO + OH reaction in fact, there is so much NO available that as NO increases, the OH + N02 termination reaction increases in importance, effectively limiting the 0H/H02 cycling and thereby decreasing the amount of O3 that can be formed. 

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