Heptametallic complexes

Fig. 18 Photoreaction of the photoproduct of [Os3(CO)io( Ji-PPh2)] with Hg2+ to yield a cyclic heptametallic complex [102]...

Heptametallic complexes, 161 centred hexagon, 161 cubanoid, 162 pentagonal bipyramid, 161 Heptane-3,5-dione, 1,1,1,2,2,6,6,7,7,7-decafluoro-metal complexes gas chromatography, 560 Heptoxime... 

There are numerous examples of dendrimers and star polymers that contain metal coordination complexes based on pyridine ligands. There is also interest in the incorporation of more than one type of metal complex into these materials. Constable and coworkers have reported the synthesis of heptametallic complexes containing six peripheral ruthenium coordination complexes and a central iron or cobalt complex. Scheme 21 illustrates the reaction of 89 with either iron or cobalt complexes to produce the heptametallic dendrimer 90. A heptametallic star-shaped complex with a CpFe -coordinated arene as the core and ruthenium Aexa-pyridine complexes at the periphery has also been reported by Astruc. ... 

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