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Halobismuthines

Halobismuthines, Dihalobismuthines, and Related Compounds. Chloro-, dichloro-, bromo-, and dibromobismuthines are best prepared by the reaction of a tertiary bismuthine and bismuth trichloride or tribromide (7,43,45,46,104—107) ... [Pg.131]

A number of compounds of the types RBiY2 or R2BiY, where Y is an anionic group other than halogen, have been prepared by the reaction of a dihalo- or halobismuthine with a lithium, sodium, potassium, ammonium, silver, or lead alkoxide (120,121), amide (122,123), a2ide (124,125), carboxylate (121,126), cyanide (125,127), dithiocarbamate (128,129), mercaptide (130,131), nitrate (108), phenoxide (120), selenocyanate (125), silanolate (132), thiocyanate (125,127), or xanthate (133). Dialkyl- and diaryUialobismuthines can also be readily converted to secondary bismuthides by treatment with an alkali metal (50,105,134) ... [Pg.132]

Hall-Petch relationship, 13 497 Haloacetic acids (HAAs), removal from drinking water, 17 806—807 Haloacetones, 1 163 Haloalkylating agents, 12 167 Haloalkylation, 12 166-168 Haloalkylbenzenes, intramolecular alkylation of, 12 169 IV-Halo-a-amino acids, 13 107 Haloaromatics, 13 573 Halobenzenes, as Friedel-Crafts arylating agents, 12 171 Halobismuthines, 4 28-29 Haloboration, 14 270 Halobrom (BCDMH,... [Pg.416]

Bismuthine, MeBiH and MCjBiH can be prepared by LiAlH reduction of halobismuthines . Yields are low,- even at — 110°C ... [Pg.116]

See other pages where Halobismuthines is mentioned: [Pg.131]    [Pg.132]    [Pg.131]    [Pg.132]    [Pg.534]    [Pg.65]    [Pg.200]    [Pg.205]    [Pg.205]    [Pg.218]    [Pg.220]    [Pg.223]    [Pg.230]    [Pg.231]    [Pg.617]   


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Halobismuthine complex salts and related compounds

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