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Halo forms, carbenes from

Carbenes and substituted carbenes add to double bonds to give cyclopropane derivatives ([1 -f 2]-cycloaddition). Many derivatives of carbene (e.g., PhCH, ROCH) ° and Me2C=C, and C(CN)2, have been added to double bonds, but the reaction is most often performed with CH2 itself, with halo and dihalocarbenes, " and with carbalkoxycarbenes (generated from diazoacetic esters). Alkylcarbenes (HCR) have been added to alkenes, but more often these rearrange to give alkenes (p. 252). The carbene can be generated in any of the ways normally used (p. 249). However, most reactions in which a cyclopropane is formed by treatment of an alkene with a carbene precursor do not actually involve free carbene... [Pg.1084]

Depending on the mode of generation, a carbene may be initially formed in either the singlet or triplet state, irrespective of its stability. Common methods used for the generation of carbenes include photolytic, thermal, or metal catalyzed decomposition of diazocompounds, elimination of halogenfrom gem-dihalides, elimination of Hx from CHX3, decomposition of ketenes, thermolysis of a-halo-mercury compounds and cycloelimination of shelf stable substrates such as cyclopropanes, epoxides, aziridines and diazirines. [Pg.93]

The reactions of P-halophospha-alkenes with carbenes provide a new route to 1-chloro-lH-phosphirines (181). Such compounds are highly reactive, and a study of nucleophilic displacement reactions at phosphorus has been facilitated by preparation of the related P-W(CO)5 complexes.The first pentacoordinate systems derived from phosphirenes, (182), have been formed in the reactions of P-halo- or P-cyano-phosphirenes with tetrachloro-o-quinone. Evidence has been presented for the rearrangement of P-chlorophosphirenium ions (183) to the vinylphosphenium ions (184)... [Pg.30]


See other pages where Halo forms, carbenes from is mentioned: [Pg.171]    [Pg.299]    [Pg.120]    [Pg.521]    [Pg.311]    [Pg.862]    [Pg.384]    [Pg.767]    [Pg.177]    [Pg.243]    [Pg.310]    [Pg.169]    [Pg.315]    [Pg.5257]    [Pg.36]    [Pg.98]    [Pg.143]    [Pg.767]   
See also in sourсe #XX -- [ Pg.258 ]




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Carbenes, halo

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