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Halides amines, prim

Alcohols from oxo compds. 20 eqs. NaBH4 added to a soln. of 5 eqs. ZrC in THF at room temp, under N2, a soln. of 4 eqs. acetophenone in the same solvent added, and the mixture stirred at room temp, for 5 h - 1-phenylethanol. Y 96%. ZrCl4 is inexpensive, easy to use, and does not affect ar. nitro compds. and bromides. F.e., also reduction of carboxylic acids, esters and halides to prim, alcohols, and amides, oximes, alkoximes, nitriles, and imines to amines, s. S. Itsuno et al.. Synthesis 1988, 995-6. [Pg.24]

Preferential formation of see. amines from halides and prim, amines... [Pg.78]

Copper and copper salts Prim, amines from halides... [Pg.132]

Phenol Prim, amines from halides 5-Aminoacridines. s. 2, 450/1 3, 384 c6h6o ... [Pg.133]

Methylmagnesium chloride Tert. from prim, amines and halides... [Pg.122]

Aniline allowed to react at -78° with trifluoromethanesulfonic acid anhydride and triethylamine in methylene diloride -> N-phenyltriflamide. Y 97%. - The protective group can be removed by reduction. F. e. and triflating agent, also Gabriel-type synthesis of prim, amines from halides via triflamides, s. J. B. Hendrickson and R. Bergeron, Tetrah. Let. 1973, 3839. [Pg.89]

Ar. prim, amines from ar. halides ArHal ArNHg... [Pg.118]

See other pages where Halides amines, prim is mentioned: [Pg.257]    [Pg.248]    [Pg.257]    [Pg.298]    [Pg.298]    [Pg.233]    [Pg.242]    [Pg.263]    [Pg.37]    [Pg.132]    [Pg.132]    [Pg.132]    [Pg.133]    [Pg.379]    [Pg.382]    [Pg.383]    [Pg.383]    [Pg.388]    [Pg.418]    [Pg.419]    [Pg.87]    [Pg.531]    [Pg.534]    [Pg.109]    [Pg.453]    [Pg.417]    [Pg.417]    [Pg.9]   
See also in sourсe #XX -- [ Pg.11 , Pg.12 , Pg.13 , Pg.14 , Pg.488 , Pg.512 , Pg.522 , Pg.527 ]



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Amines, prim

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