H2SO4 at 10 mVs

Fig.2- Cyclic voltammogram far oxidation of COad adsorbed at 50 mV on a chemically platinized Pt electrode in 3 M H2SO4 at 10 mV/s. 

AuNPs were electrodeposited onto a clean gold electrode surface by electrodeposition method. Where, the gold electrode was twice cycled in the potential range + 1.1 V to 0 V in deoxygenated solution containing 0.77 mM HAUCU in 0.5 M H2SO4 at 10 mV s"1 scan rate. This AuNPs modified electrode was then immersed into a 300 pi solution of 0.1 M phosphate buffer (PBS) pH 8, containing 60 pg of AChE for 24 h at 4 °C. Finally this AChE modified... 

Figure 12.4 A series of SFG spectra in the CO stretch region of chemisorbed CO on polycrystalline Pt in a CO-free 0.1 M H2SO4 electrolyte. The atop spectra were fit to (12.5) (see text) to extract the amplitude, frequency, and width [Lu et al., 2005 Lagutchev et al, 2006] (each displayed data point is the average of three or five spectra). The electrode potential was swept at a rate of 5 mV/s, and SFG spectra were obtained every 200 ms. Spectra were obtained at 1 mV intervals, but, to avoid congestion in the plot, averaged spectra are displayed at 10 mV intervals in the pre-oxidation region (V < 0.43 V) and at 3.3 mV intervals in the oxidation region (V > 0.43 V) [Lu et al., 2005].

Fig. 4-14 Cyclic voltammograms of a smooth Pt-Sn electrodes in 3 M H2SO4 with COad at 10 mV/s.

Figure 2.6 In situ STM images of a freshly prepared Au(lll) substrate showing the initial thermally induced reconstruction rows (visible as stripes) for different surface areas [2.10]. System Au(lll)/ 10 M H2SO4 at = - 150 mV vs. SCE and T = 298 K. (a) top view of an atomically smooth surface, and (b) 3D representation of a face with a monatomic step. Reprinted by permission of Kluwer Academic Publishers.

Fig. 3. STM images of the passive film formed on Cr(l 10) in 0.5M H2SO4 at +500 mV/RHE. The left image shows the disordered protrusions of nanoscopic dimensions. The right images show a small ordered domain assigned to a nanocrystal of oxide (a-Cr203(0001)) at two different magnifications.

Fig. 2.41 Cadmium deposits obtained fimn (a) 1.0 M CdS04 in 0.50 M H2SO4 at 12 mV Deposition time 15 min, (b) 0.10 M CdS04 in 0.50 M H2SO4 at 120 mV. Deposition time 45 s, and Zinc deposits obtained by deposition at 35 mV from 0.10 M zincate solution in 1.0 M KOH. Deposition time (c) 7 min and (d) 15 min (Reprinted from Refs. [7, 13, 112] with kind permission from Springer and Ref. [113] with permission from the Serbian Chtanical Society)...

Fig. 3.11 A time-resolved series of selected ART-FTIR integrated peak intensities as measured during potential cycling on (a) polycrystalline Pt and (b) 60 % antimony (Sb) adatom covered polycrystalline Pt in 0.5 M H2SO4 and 0.1 M formic acid at 10 mV s. From the top-down the series of plots are as follows the current response, COl, COb, and framate [27]...

Fig. 1. Polarization curves recorded at 10 mV s for O2 reduction in 02 8aturated 0.5 M H2SO4 onaa)(—)pc-Au,b)( )po-Aa-<-0.3 pNaf electrode.

Figure 12.16 Potential dependent SFG spectra (a) and the Stark tuning plot (b) from chemisorbed CO on Pt nanoparticles in a CO-saturated 0.1 M H2SO4 electrolyte. Each spectrum was acquired for 10 s (forward scan data only are shown). The potential was scanned from — 0.20 to 0.70 V (vs. Ag/AgCl) at 1 mV/s. Pt nanoparticles were of approximately 7 nm size, and were immobilized on an Au disk.

Figure 13.1 Electrooxidation of COad and Ci adsorbate layers pie-adsorbed on a Pt/Vulcan thin-film electrode (7 JLgptCm , geometric area 0.28 cm ) in 0.5 M H2SO4 solution during a first positive-going potential scan, and subsequent response of the faradaic (a) and m/z = 44 ion current (b) to the electrode potential in the thin-layer DBMS flow cell. The potential scan rate was 10 mV s and the electrolyte flow rate was 5 p,L s at room temperature. The respective adsorbates were adsorbed at 0.11 V for 10 minutes from CO-saturated solution (solid line), 0.1 M HCHO solution (dashed line), 0.1 M HCOOH solution (dash-dotted line), and 0.1 M CH3OH solution (dash-double-dotted line).

Fig. 33. Cyclic voltammogram of a ethanethiol-covered Au(lll) electrode in 0.1 M H2SO4 + 0.7 mM CUSO4. Scan rate 10 mV s-1. At such a scan rate, the kinetically strongly hindered Cu upd is shifted into the opd range (peak at -0.2 V) [121],...

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