Guidelli

Guidelli R 1986 Trends in interfaciai Eiectrochemistry (NATO ASi Series 179) ed A Fernando Silva (Dordrecht Reidel)... 

Guidelli and co-workers336-338 measured the potential of zero charge by chronocoulometry. They found that the pzc was independent of the electrolyte concentration in both NaC104 and Na2S04. However, Ea=0 in the presence of sulfates was ca. 40 mV more negative. These authors have explained this apparent discrepancy in terms of the perturbation of the solvent structure at the interface by the ions at the electrode surface, which are, however, nonspecifically adsorbed. 

Figure 22. Correlations between the interfacial term, AX, derived from Fig. 14, and the enthalpy of formation of the oxide MO, corrected for the work to break metal-metal bonds. I, II, in mean first, second, and third periods of the periodic table of elements. From Ref. 26, updated. (From R. Guidelli, ed, Electrified Interfaces in Physics, Chemistry, and Biology, p. 252, Fig. 3. Copyright 1992 Kluwer Academic Publishers. Reproduced with permission.)...

S. Trasatti, in Electrified Interfaces in Physics, Chemistry and Biology, R. Guidelli, ed., Kluwer, Dordrecht, 1992, p. 229. 

G. Aloisi, R. Guidelli, R. A. Jakson, S. M. Clark, andP. Barnes,/.Electroanal. Chem. 887 206(1986)131. 

Kolb, reconstruction of, 85 Gold-solution interface (Clavilier and Nguyen Van Huong), 77 Guidelli, and the methods for the determination of the potential of zero charge, 63... 

Guidelli, and methods for the determination of, 63 Heusler and Lang, anisotropic surface potential and, 34 and the impedance method, 35 importance, 5... 

Models for the compact layer of the metal-electrolyte interface have become more and more elaborate, providing better and better representations of observed electrocapillary data for different metals, solvents, and temperatures, but almost always leaving the metal itself out of consideration, except for consideration of image interactions of the solvent dipoles. For reviews of these models, see Parsons,13 Reeves,14 Fawcett et a/.,15 and Guidelli,16 who gives detailed discussion of the mathematical as well as the physical assumptions used. 

Guidelli,16 reviewing work on the capacitance of the metal-electrolyte interface, writes the equation for calculating capacitances from models for the inner layer as ... 

R Guidelli, in Trends in Interfacial Electrochemistry, Ed by A Fernando Silva, Reidel, Dordrecht, 1986, p 387... 

---