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Growth Catalyst-Transfer Polycondensations

Chain-growth catalyst-transfer polycondensation (CTP) is a rapidly developing polymerization method, as it allows, in many cases, the above-mentioned limitations of step-growth polymerizations to be overcome. CTP provides a straightforward access to well-defined conjugated homopolymers (e.g., polythiophenes (1), polyfluorenes (2), polyphenylenes (3), etc.), alternate donor-acceptor copolymer e.g., 4) and all-conjugated block polymers (e.g., 5), Chart 20.1. [Pg.466]

Miyakoshi, R., A. Yokoyama, and T. Yokozawa. 2005. Catalyst-transfer polycondensation mechanism of Ni-catalyzed chain-growth polymerization leading to well-defined poly(3-hexylthiophene). JAm Chem Soc 127 (49) 17542-17547. [Pg.396]

Beryozkina T, Senkovskyy V, Kaul E, Kiriy A (2008) Kumada catalyst-transfer polycondensation of thiophcaie-based oligomers robustness of a chain-growth mechanism. Macromolecules 41 7817-7823... [Pg.32]

Wu S, Huang L, Tian H, Geng Y, Wang F (2011) LiCl-promoted chain growth Kumada catalyst-transfer polycondensation of the reversed thiophene monomer. Macromolecules 44 7558-7567... [Pg.35]

Keywords Catalyst-transfer Chain-growth condensation polymerization Living polymerizatiOTi Polycondensation jr-Conjugated polymers... [Pg.191]

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