Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Group 8 VIII binuclear complexes

The bifunctional ligand 2(diphenylphosphino)pyridine can be used to construct binuclear metal complexes in a stepwise fashion/ With Group VIII metal ions, this ligand appears to preferentially bind via the phosphorus atom. From this reaction, a host of metal complexes, very similar to those of triphenylphosphine, are available. All have the potential for binding a second metal ion through the uncoordinated pyridine nitrogen. Some of the reactions that result in the formation of binuclear complexes are shown... [Pg.204]

Other common species with this mode of coordination are the binuclear group 9 (VIII) complexes [M2(S2CNR2)5]" ", formed upon oxidation of tris(-dithiocarbamate) complexes, [M(S2CNR2)3] (M = Co, Rh) (Eq. 45) (302-311). [Pg.109]

See other pages where Group 8 VIII binuclear complexes is mentioned: [Pg.180]    [Pg.254]    [Pg.622]    [Pg.167]    [Pg.7]    [Pg.315]    [Pg.168]    [Pg.237]    [Pg.215]   
See also in sourсe #XX -- [ Pg.308 , Pg.309 , Pg.310 ]



SEARCH



Binuclear

Binuclear groups

Group 8 (VIII complexes

Groups, viii

© 2024 chempedia.info