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Metallocenes group

Rosenblum M (1965) Chemistry of the iron group metallocenes (part I) Wiley, New Y ork... [Pg.91]

For a review of cyclopentadienone derivatives and of attempts to prepare the parent compound, see Oglianiso, M.A. Romanelli, M.G. Becker, E.I. Chem. Rev., 1965,65,261. For a monograph on metallocenes, see Rosenblum, M. Chemistry of the Iron Group Metallocenes Wiley NY, 1965. For reviews, see Lukehart, C.M. Fundamental Transition... [Pg.84]

Rosenblum, M., Chemistry of the Iron Group Metallocenes. Wiley, New York. 1965. [Pg.205]

Rosenblum M, Abbate FW (1966) The problem of metal atom participation in electrophilic substitution reactions of the iron group metallocenes. J Am Chem Soc 88 4178 184... [Pg.170]

Reviews of quantum chemical calculations on main group metallocenes that include group 2 species are available.388 389... [Pg.137]

Chemistry of the iron group metallocenes Ferrocene, ruthenocencand osmocene. Part. I. John Wiley and Sons, Intcrscicnce New York 1965. [Pg.132]

Electroionic signals are generated by electrochemical interconversion of a selective receptor molecule containing a redox-active group (metallocene, quinone, etc.) between states of low and high affinity for a given substrate (see Sections 6.4.1 and 8.3.1). [Pg.135]

Rosenblum, M. Chemistry of Iron Group Metallocenes Ferrocene, Ruthenocene, Osmocene. John Wiley New York, London, 1965. [Pg.123]

Metal-Carbon Distances in Linear Main-Group Metallocenes... [Pg.140]

Fig. II. Variations in the spread of M-C distances (AM C) in main-group metallocenes with cyclopentadienyl rings of different steric bulk. Fig. II. Variations in the spread of M-C distances (AM C) in main-group metallocenes with cyclopentadienyl rings of different steric bulk.
Table IV contains calculated 8 values for bent main-group metallocenes there is not a strong correlation with the substituents on the ring. Thus, for the case of stannocenes, both the Cp and the Ph5Cp ring in [Sn (C5Ph5)Cp]120 have 8 = 82.5°, and the highly substituted [Sn(C5(/-Pr)4H)2]79 has 8 = 83.6°, whereas one of the two forms of [SnCp2] has 8 = 85.2°.17 Clearly, packing effects can influence the angle, as the other [SnCp2] molecule has 8 = 82.5°. Table IV contains calculated 8 values for bent main-group metallocenes there is not a strong correlation with the substituents on the ring. Thus, for the case of stannocenes, both the Cp and the Ph5Cp ring in [Sn (C5Ph5)Cp]120 have 8 = 82.5°, and the highly substituted [Sn(C5(/-Pr)4H)2]79 has 8 = 83.6°, whereas one of the two forms of [SnCp2] has 8 = 85.2°.17 Clearly, packing effects can influence the angle, as the other [SnCp2] molecule has 8 = 82.5°.
Fig. 7. Frontier orbital stabilization in the bending of a main group metallocene. Fig. 7. Frontier orbital stabilization in the bending of a main group metallocene.
See other pages where Metallocenes group is mentioned: [Pg.257]    [Pg.121]    [Pg.72]    [Pg.48]    [Pg.84]    [Pg.154]    [Pg.153]    [Pg.118]    [Pg.119]    [Pg.127]    [Pg.127]    [Pg.131]    [Pg.132]    [Pg.132]    [Pg.139]    [Pg.140]    [Pg.321]    [Pg.388]    [Pg.157]    [Pg.177]    [Pg.156]    [Pg.118]    [Pg.119]    [Pg.127]    [Pg.127]   
See also in sourсe #XX -- [ Pg.525 ]

See also in sourсe #XX -- [ Pg.578 , Pg.579 , Pg.581 , Pg.582 , Pg.591 , Pg.592 , Pg.594 , Pg.600 , Pg.601 ]

See also in sourсe #XX -- [ Pg.853 , Pg.855 , Pg.865 , Pg.866 , Pg.868 , Pg.872 , Pg.876 ]



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