Group 6 metal halide clusters molecular structure

Redox Chemistry and Photophysics of the Group 6 Metal Halide Clusters Molecular and Electronic Structure of the Group 6 Metal Halid Clusters Group 5 Metal Halide Clusters A. Synthesis of Cluster Core... 

E. Molecular and Electronic Structure of the Group 6 Metal Halid Clusters... 

Redox Chemistry of the Group 5 Clusters Ligand Substitution Electronic and Molecular Structure Niobium Iodide Clusters NbJJ"-Materials Chemistry Derived from Soluble Metal Halide Clusters A. Higher Nuclearity Clusters Supported Cluster Materials Charge-Transfer Salt Complexes Extended Solids Chemically Modified Surfaces... 

As holds for other cluster systems, certain magic cluster electron counts exist, which indicates for a certain cluster-halide ratio and interstitial present the filling of all bonding molecular orbitals and therefore the thermodynamically most stable situation. For main group interstitial atoms these are 14 cluster-based electrons whereas for transition-metal interstitials the magic number is 18 [1, 10-12]. All of these phases are synthesized by high-temperature solid-state chemical methods. A remarkable variety of different structure types has been... 

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