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Group inverse operation

The double-group reflection operators are similarly formed by taking the product of the double-group inversion operator with each of the possible C2 operations, to give two reflections. [Pg.91]

Invariance principle, 664 Invariance properties of quantum electrodynamics, 664 Inventory problem, 252,281,286 Inverse collisions, 11 direct and, 12 Inverse operator, 688 Investment problem, 286 Irreducible representations of crystallographic point groups, 726 Isoperimetric problems, 305 Iteration for the inverse, 60... [Pg.776]

The factor group Dzh of orthorhombic Sg includes an inversion operation therefore, the g-u exclusion principle works resulting in modes of either Raman (gerade, g) or infrared activity (ungerade, u). [Pg.46]

HP-3 FGI, in order to introduce a C=0 group, modify a double bond or to proceed to a "reactivity inversion" operation Umpolung) in dissonant bifunctional relationships (see below iii-a). [Pg.330]

INVERSE are the inverse operator list, and the Gensym symbol for it, respectively. The CLASS property value is another Gensym atom which has as its value a list of all of the operators in that class. (In this simple case, the value of // CLS-1 is the list (// GRP-1), etc.) The remaining pairs in each property list represent the group multiplication table. For any particular group multiplication, an element of the group list at the top of Table I pertains to the right operator, the property indicator pertains to the left operator, and the property value pertains to the product. For example, for the product of the permutation operator (123) with itself,... [Pg.180]

Equations (59) and (62) ensure that the analytical representations of jly, have the correct transformation properties under the inversion operation E. Since the appropriate symmetry group for NH3, can be written as the direct... [Pg.228]

Definition IV 3.2. Soient S un schema, G un S-schema en groupes qui opere sur un S-schema X et soit L un faisceau inversible sur X. Nous dirons que L satisfait h (C) si L verifie les conditions equivalentes de la proposition IV 3.1. [Pg.71]

Thus, the problem of enumeration and construction of projective fullerenes reduces simply to that for centrally symmetric conventional spherical fullerenes. The point symmetry groups that contain the inversion operation are Q, C, h, (m even), Dmh (m even), Dmd (m odd), 7, Oh, and 7. A spherical fullerene may belong to one of 28 point groups ([FoMa95]) of which eight appear in the previous list C,-, C2h, Dm, Da, D3d, Du, 7, and /. Clearly, a fullerene with v vertices can be centrally symmetric only if v is divisible by four as p6 must be even. After the minimal case v = 20, the first centrally symmetric fullerenes are at v = 32 (Dm) and v = 36 (Dm). [Pg.42]

Other groups may be handled in a similar manner to O in Example 8.1-1. For improper rotations, the two rules formulated previously hold also for double groups (Box 8.1). If the group contains the inversion operator, even or odd parity is indicated by a superscript of + or —in Bethe s notation and by a subscript g or u in Mulliken-Herzberg notation. [Pg.151]

Most electronic transitions between different states of the f-electrons are dominated by electric dipole transitions. Only in exceptional cases like Eu(III), magnetic dipole transitions are found to be as strong as electric dipole transitions. However, in the case of an f element, electric-dipole transitions between the 4fw states are forbidden because the parity of initial and final state is conserved. Only when the f element is embedded in a crystal providing a point group symmetry that does not contain the inversion operation, these transitions can be observed readily. [Pg.559]

In addition, the spin-inversion symmetry is available for M=0. The operator 6 is defined when it acts on a Slater determinant, transforming all spin-up sites to spin-down sites and vice versa. Thus the space of M=0 is invariant under the group [7,0] which consists of identity and spin-inversion operations. Let us discuss the 20 determinants of M=0 for trimethylene-cyclopropane, the spin-inversion operator transforms A to B, C to D, and E to F, or vice versa, respectively. Under the compounded groups [/,d], a pair of Slater determinants that are transformable via the spin-inversion operation should combine, as represented by A B, C D and E F respectively. Thus blocks A and A2 are further reduced to two 3x3 and two lxl blocks... [Pg.579]


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See also in sourсe #XX -- [ Pg.389 ]




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Group inversion

Group operation

Inverse operation

Inversion operation

Operator inverse

Operator inversion

Symmetry operations, group inverse

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