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Group-IIB Bonds

Formation of group-IIIB-group-IB and -IIB element bonds is limited almost exclusively to the element B and is observed predominantly in metalloboranes and metallocarboranes. The boron-IB and boron-group-IIB bonding interactions either are of the a type or can be described as multicenter bonds ... [Pg.47]

The synthesis of compounds containing boron-group IIB bonds also occurs by two pathways. The most convenient method is using anionic borane or carboranc species, as in the group-IB case, to react with Zn, Cd, or Hg halides. Moreover, reactions between organometallic compounds (Zn, Cd) with unchanged boranes arc also realized, so Zn and Cd decaboranes, e.g., MB H 2 n solvent (M = Zn, Cd), result from reactions of decaborane(14) with MRj . [Pg.50]

Carbon-Group-IIB Bonds 5.7.2.3. from Metal Salts 5.7.2,3.1. with Organometallics. [Pg.336]

See other pages where Group-IIB Bonds is mentioned: [Pg.47]    [Pg.48]    [Pg.51]    [Pg.52]    [Pg.322]    [Pg.323]    [Pg.324]    [Pg.325]    [Pg.326]    [Pg.327]    [Pg.328]    [Pg.329]    [Pg.330]    [Pg.331]    [Pg.332]    [Pg.333]    [Pg.334]    [Pg.335]    [Pg.338]    [Pg.340]    [Pg.342]    [Pg.344]    [Pg.346]   


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1//IIB

Group-IIB

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