Group 18 elements reaction with, phosgene

It is remarkable how pooriy documented, on the whole, are the reactions of phosgene with the main group elements. There are very few classical studies of the reactivity of the elements with phosgene at low temperature, although the number of purely physical investigations are increasing. 

Reactions of phosgene with Group 4, Group 5 and Group 6 elements... 

From the reactions of phosgene with fluorides of the main group elements... 

Looking at Scheme 4.1, one can see that in chloroformylation, carhonylation, and chlorination reactions, phosgene reacts with nucleophilic groups Y-Z of monovalent type Z is always H, and Y is represented by the classical nucleophilic elements the reactivity (nucleophilicity) of the nucleophiles increases according to thiols <... 

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