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Group 16 Alkali Metal Bonded Complexes

Group 15 Alkali Metal Bonded Complexes 2.01.4.1 N-M Bonded Complexes... [Pg.26]

Group 11 alkali metal bonded complexes, Group 1-Group 11, 2, 50... [Pg.111]

Group 14 alkali metal bonded complexes Group 1-Group 14, 2, 55 Zintl clusters, 2, 24... [Pg.111]

The transition metal-group IV metal bond can be formed both by attack of a transition metal anion at a group IVg halide and by attack of an alkali metal derivative of the group IV element at a suitable transition metal complex. [Pg.80]

Significantly fewer unsupported and structurally characterized alkali metal-TM complexes are known, though they show similar motifs compared with their main group counterparts. For example, the cuprate complex [(THF)2Na-Cu(SFBu3)2j, 7, exhibits an almost linear Si—Cu—Si fragment (175.26(5)°) and a Na-Cu bond of 2.7393(18) A [68]. The rare 2,2 -biphosphinine-coordinated Ru complex 8 has been obtained from reduction of the corresponding Ru" chloride complex with sodium naphthalenide in DME. This has a Ru-Na bond of 3.072(2) A in the solid state [69] and is effective in salt metathesis reactions with Mel or RjSnCl (R = Me, Ph) to give substituted Ru" complexes. [Pg.28]

Several tri(cyclopentadienyl)tin(ll) and lead(ll) complexes have been prepared with alkali metal cations. The arrangement of Cp rings around the metal is in a paddle wheel configuration the alkali cation is bound to Cp and not Sn or Pb, further supporting the view of a weak alkali metal group 14 bond. Representative examples of these compounds include (77S-Cp)2E(/r-Cp)-Na(PMDTA) (E = Sn 230, Pb 231).239 240... [Pg.25]

See other pages where Group 16 Alkali Metal Bonded Complexes is mentioned: [Pg.111]    [Pg.111]    [Pg.111]    [Pg.28]    [Pg.57]    [Pg.69]    [Pg.68]    [Pg.80]    [Pg.950]    [Pg.12]    [Pg.110]    [Pg.1596]    [Pg.25]    [Pg.31]    [Pg.27]    [Pg.66]    [Pg.81]    [Pg.460]    [Pg.27]    [Pg.27]    [Pg.163]    [Pg.340]    [Pg.5]    [Pg.371]    [Pg.127]    [Pg.78]    [Pg.1007]    [Pg.70]    [Pg.94]    [Pg.151]    [Pg.1007]    [Pg.311]    [Pg.1266]    [Pg.236]    [Pg.10]    [Pg.16]    [Pg.26]    [Pg.26]    [Pg.27]    [Pg.35]    [Pg.37]   


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