Ground-state dissociation energy

The adopted value of the ground state dissociation energy for Beg(g), level quantum mechanical calculation by Lengsfleld, et al, ( ). Using this value and the recommended value for A H"(Be, g, 0 K)... 

Using the adopted value of the ground state dissociation energy for CSgCg),... 

The (total) ground-state dissociation energy Dq of a molecule is the energy needed to dissociate the molecule in its ground vibrational state to atoms in their ground states. Dq differs from the equilibrium dissociation energy by the zero-point... 

Vibration frequency in ground state, Dissociation energy m ground state, volts Internuclear distance in ground state, A... 

Figure 3.11 Birge-Sponer plot of AG(v) versus v for the electronic ground state of Nag. The area under the AG(v) curve yields the ground state dissociation energy D. Linear extrapolation of the points for low v (straight line) would clearly yield a gross overestimate of Nonlinear extrapolation of the points exhibited for 0 < v < 45 (P. Kusch and M. M. Hessel, J. Chem. Phys. 68 2591 (1978)) leads to an improved estimate of D. A still better approximation to can be made by analyzing vibrational levels for v up to 55 from the more recent Na2 fluorescence spectrum shown in Fig. 4.1.

Metal Metal oxide Dissociation energy, kcal/mole Metal (ground state) Metal oxide (ground state) Dissociation energy, kcal/mole... 

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