Gold l 11 Complexes

With tripodal tris(diphenylphosphinito)fluoroborate [FB(OPPh2)3] ligands and gold(l) complexes two structurally related, completely inorganic cages 81 and 82 are known (Fig. 22) [118, 119]. 

Supramolecular Entities ofTrinuclear Gold(l) Complexes Sandwiching Small Organic Acids 31... 

Banditelli, G., Bandini, A.L., Bonati, F. and Goel, R.G. (1982) Some New Gold(l) complexes with bulky ligands. Gazzetta Chimica Italiana, 112, 539. 

ROO- + Au -OH — ROOM Au"-0 Scheme 2.8 Oxidation of alkanes with hydrogen peroxide catalyzed by gold(lll) and gold(l) complexes. 

Schroder, D., Schwarz, H., Hrusak, J. and Pyykkd, P. (1998) Cationic gold(l) complexes of xenon and of ligands containing the donor atoms oxygen, nitrogen, phosphorus, and sulfur. Inorganic Chemistry, 37, 624—632. 

Hertwig, R.H., Hrusak, J., Schroder, D., Koch, W. and Schwarz, H. (1995) The metal-ligand bond strengths in cationic gold(l) complexes. Application of approximate density functional theory. Chemical Physics Letters, 236, 194-200. 

Arias, J., Baradaji, M. and Espinet, P. (2008) Mononuclear, dinuclear, and hexanuclear gold(l) complexes with (aza-15-crown-5) Dithiocarbamate. Inorganic Chemistry, 47, 1597-1606. 

Ovejero, P., Mayoral, M.J., Cano, M. and Lagunas, M.C. (2007) Luminescence of neutral and ionic gold(l) complexes containing pyrazole or pyrazolate-type ligands. Journal of Organometallic Chemistry, 692, 1690-1697. 

Recently Teles found that cationic gold(l) complexes of the general type [L-Au ] (where L is a phosphine, a phosphite or an arsine) were excellent catalysts for the ad-... 

A review of the photochemistry of gold(lll), and of gold(l), complexes deals both with substitution and redox reactions (263). 

Late transition metal-catalyzed processes also proved to be very useful tools for formation of the C-O bond of the 1,3-oxazine ring from the corresponding alkynes. In the presence of 1-5 mol% of a cationic gold(l) complex, A -BOC-protected alkynylamines 450 were converted to 6-alkylidene-l,3-oxazin-2-ones 451 under very mild conditions (Equation 49) <2006JOC5023>. 

Figure 1.16 Dinuclear heterobridged diphosphine gold(l) complexes.

Figure 1.17 Gold(l) complexes with tritertiary phosphine or phosphine-arsine ligands.

Figure 1.24 Some gold(l) complexes with bidentate sulfur ligands.

Figure 1.28 Three-coordinate gold(l) complexes with diphosphine ligands.

Figure 1.31 Oligomeric gold(l) complexes with carbon donor ligands.

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