Gold arsine complexes

The number of gold complexes containing tertiary phosphines, arsines, or stibines as ligands is large because of the wide use of the fragment AuL+, mainly with L = PPh3, in the synthesis of... [Pg.1042]

AsFe04C 2H]5, Iron, tetracarbonyl-(triphenylarsine)-, 26 61 As2C Hu, Arsine, 1,2-phenylenebis-(dimethyl)-gold complex, 26 89 As4Au2F,( C,2H1 , Gold(I), bis[ 1,2-... [Pg.411]

C1bHi5As, Arsine, triphenyl-iron complex, 26 61 C H 5OjP, Triphenyl phosphite ruthenium complex, 26 178 CuHijP, Phosphine, triphenyl-cobalt complex, 26 190—197 cobalt-gold-ruthenium, 26 327 gold complex, 26 90, 325, 326 gold-manganese complex, 26 229 iridium complexes, 26 117-120, 122-125, 201, 202... [Pg.416]

AsjC iHn, Arsine, 1,2-phenylenebis(di-methyl-, gold complex, 26 89 As,H40, Rb4W2,, 4H,0, Tungstate (4-). aquadihydroxohenhexacontaox-obis(trioxoarsenato(Ill)]henicosa-, te-trarubidium, tetratricontahydrate, 27 113... [Pg.373]

AsFe04C22H,5, lron(0), tetracarbonyl(tri-phenylarsine)-, 26 61, 28 171 AsjCijHij, Arsine, l,2-phenylenebis(di-methyl-, gold complex, 26 89 nickel complex, 28 103 AsjCljNRuSCjgHjo, Ruthenium(II), tri-... [Pg.341]

The arsine complex (Ph3As)AuOSiMea was similarly prepared. The tris-(phosphine)-copper and -silver complexes and the gold complexes are monomeric, with two-co-ordinate metal the mono- and bis-(phosphine)-copper and -silver siloxanes are oligomers (38) and (39), with bridging... [Pg.356]

C10H15N, Benzenemethanamine, N,N,4-trimethyl-, lithium complex, 26 152 C10H15P, Phosphine, diethylphenyl-, nickel complex, 28 101 platinum complex, 28 135 CioHigAsi, Arsine, 1,2-phenylenebis(dimethyl-, gold complex, 26 89 nickel complex, 28 103 CioHie, 1,3-Cyclopentadiene, 1,2,3,4,5-pen-tamethyl-, 28 317 chromium complex, 27 69 cobalt complexes, 28 273, 275 iridium complex, 27 19 samarium complex, 27 155 titanium complex, 27 62 ytterbium complex, 27 148 CioH,gBrN04S, Bicyclo[2.2.1]heptane-7-methanesulfonate, 3-bromo-1,7-di-methyl-2-oxo-, U.IRHENDO, ANTPi]-, ammonium, 26 24... [Pg.395]

The phosphine and arsine complexes of gold(I) have been intensively studied since the early 1970s. The possibilities of coordination numbers between 2 and 4 have been explored, though the use of bulky ligands is less essential than with the isoelectronic M(PR3)2 (M = Pd, Pt) compounds and the coordination numbers depend on both steric and electronic factors [71]. [Pg.292]

Gold (I) complexes of bidentate phosphines and arsines like... [Pg.304]

Alkene complexes Alkynyl complexes Ammine complexes Aqueous chemistry Arsine complexes Auranofin Auride ion Aurophilicity Binary compounds Bond lengths acetylacetonate complex alkyls and aryls ammine complexes carboxylates cyanide complexes dialkyl sulphide complexes dithiocarbamates to gold... [Pg.363]

Recently Teles found that cationic gold(l) complexes of the general type [L-Au ] (where L is a phosphine, a phosphite or an arsine) were excellent catalysts for the ad-... [Pg.204]

Gold(I) complexes of the type [AuCl(PPh3)ra] (n= 1, 2) or [Au(N03)(PPh3)] show an excellent performance towards oxidative addition carbonylation or aromatic amines to form corresponding carbamates, and also towards the carbonilation of aliphatic amines to produce either alkylureas or formamides.2552,2553 Cationic gold(I) compounds of the type [AuL]+ where L = phosphine, phosphite, or arsine are excellent catalysts for the addition of alcohols to alkynes.2554... [Pg.1047]

Kneen (4, 31) prepared a series of copper(I), silver(I) and gold(I) complexes containing olefinic tertiary phosphines and arsines for several reasons ... [Pg.23]

Figure 1.17 Gold(l) complexes with tritertiary phosphine or phosphine-arsine ligands.

Linear Gold(I) Complexes with Monodentate Phosphine, Arsine or Stibine Ligands 882... [Pg.861]

COMPLEXES OF GOLD(III) WITH PHOSPHINE AND ARSINE AND STBINE LIGANDS 897... [Pg.862]

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