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Glycosyl derivatives hydrolysis

Table 3.3 Kinetic isotope effects for hydrolysis of various glycosyl derivatives. The isotopic quasi-racemate method was used for all measurements except those for AMP, where the remote label method was used. Table 3.3 Kinetic isotope effects for hydrolysis of various glycosyl derivatives. The isotopic quasi-racemate method was used for all measurements except those for AMP, where the remote label method was used.
Hydrolysis of colominic acid (from E. coU), a naturally occurring poly a-(2- 8)-linked polysialic acid, gives Neu5Ac-a-(2- 8)-Neu5Ac which has been used to prepare the glycosylating derivatives (94) and (95). ... [Pg.37]

Salicylic acid was used for phosphite protection in the synthesis of glycosyl phosphites and phosphates. This derivative is very reactive and readily forms a phosphite upon treatment with an alcohol or a phosphonic acid upon aqueous hydrolysis. ... [Pg.695]

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See also in sourсe #XX -- [ Pg.75 ]



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0- derivatives hydrolysis

Glycosyl hydrolysis

Glycosylation derivatives

O-Glycosyl derivatives hydrolysis with acid

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