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Glucose Knoevenagel reaction

What is described as a domino Knoevenagel-hetero-Diels-Alder reaction , involving the reaction of the glucose-derived aldehyde 93 with a 1,3-dicarbonyl compound in presence of either proline or ethylenediammonium acetate, leads to the doubly annulated 5 6 6-fused compound 94 (Scheme 30) <2004S1150>. If the dicarbonyl compound is Meldmm s acid, however, the sequence is completed by spontaneous elimination of acetone and carbon dioxide from the Diels-Alder adduct, to give compound 95 <2005ASC1353>. [Pg.878]

See other pages where Glucose Knoevenagel reaction is mentioned: [Pg.322]    [Pg.45]    [Pg.354]    [Pg.354]    [Pg.382]    [Pg.303]    [Pg.354]    [Pg.382]    [Pg.164]    [Pg.758]    [Pg.147]    [Pg.3]    [Pg.36]    [Pg.149]    [Pg.8]   
See also in sourсe #XX -- [ Pg.2 , Pg.354 ]

See also in sourсe #XX -- [ Pg.354 ]

See also in sourсe #XX -- [ Pg.354 ]

See also in sourсe #XX -- [ Pg.2 , Pg.354 ]

See also in sourсe #XX -- [ Pg.354 ]



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Glucose reaction

Knoevenagel reaction

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