GLUCOPYRANOSIDE, METHYL 6-BROMO-6-DEOXY, 4-BENZOATE

Glucopyranoside, methyl 4,6-0-benzylidene-, a-D-, 65, 243 GLUCOPYRANOSIDE, METHYL 6-BROMO-6-DEOXY, 4-BENZOATE, a-D-, 65, 243 Glucopyranoside, methyl 4,6-0-(phenylmethylene)-, a-D-, 65, 243 Glucopyranosyl bromide, 2,3,4,6-tetraacetate, a-D-, 65, 236 Glucopyranosyl bromide tetraacetate, a-D-, 65, 236... 

Methyl 4-0-benzoyl-6-bromo-6-deoxy-a-D-g1ucopyranoside Glucopyranoside, methyl 6-bromo-6-deoxy-4-benzoate, a-D- (8) glucopyranoside, methyl 6-bromo-6-deoxy, 4-benzoate, a-D- (9) (10368-81-7)... 

Reaction of methyl 4,6-0-benzylidene-a-D-glucopyranoside or -a-o-galactopyranoside with A-bromosuccinimide in dry carbon tetrachloride led to the 6-bromo-6-deoxy 4-benzoates, in a reaction which appears to involve, initially, free-radical oxidation of the benzylidene group by bromine atoms. This may be followed either by a free-radical attack (20)... 

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