Glass transitions of amorphous structural domains

According to Eisenberg,225 the glass transition is perhaps the most important single parameter related to applications of amorphous polymers, as it greatly affects their 

Tg (mobile amorphous) Tg (rigid amorphous) Tm (rigid crystalline)- Although this polymeric view 

It has also been noted that the Tg increases with increasing crystallinity,27,242 which is 

The composition dependence of Tg of binary (starch-water) or ternary (starch-sugar-water) blends, assuming component miscibility and the absence of crystallinity 

The relationship between Tg and molecular weight, M, is often described by the Fox and Flory equation 266 Tg = T/XJ - K/M, where T/XJ is the glass transition temperature of the polymer with infinite molecular weight and K is a constant characteristic of the polymer. For the malto-oligomer series, a double reciprocal plot of 

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